| Date | Player | Pos | From | To | Value/Type |
| 12/08/2013 | Jonas Ramalho | Defender | Athletic | Girona | Loan |
| 12/08/2013 | Natxo Insa | Midfielder | Celta | Antalyaspor A.S. | Free |
| 08/08/2013 | Galarreta | Midfielder | Athletic | Mirandés | Loan |
| 08/08/2013 | Hélder Postiga | Forward | Zaragoza | Valencia | € 3M |
| 07/08/2013 | Xavi Torres | Midfielder | Levante | Betis | N/A |
| 05/08/2013 | Roberto Soldado | Forward | Valencia | Tottenham | € 30M |
| 02/08/2013 | Joaquin Larrivey | Forward | Atlante | Rayo Vallecano | Loan |
| 25/07/2013 | Marcos Angeleri | Midfielder | Estudiantes | Malaga | Free |
| 25/07/2013 | Sergio Asenjo | Goalkeeper | Atlético Madrid | Villarreal | Loan |
| 24/07/2013 | Gonzalo Higuaín | Forward | Real Madrid | Napoli | € 37M |
| 22/07/2013 | Naldo | Defender | Granada | Udinese | N/A |
| 21/07/2013 | Raúl Albiol | Defender | Real Madrid | Napoli | € 12M |
| 20/07/2013 | Trejo | Midfielder | Sporting G | Toulouse FC | N/A |
| 20/07/2013 | Fabinho | Defender | Real Madrid | AS Monaco | Loan |
| 19/07/2013 | Daniel Pudil | Defender | Granada | Watford | N/A |
| 18/07/2013 | Cata Díaz | Defender | Atlético Madrid | Boca Juniors | Free |
| 17/07/2013 | Negredo | Forward | Sevilla | Manchester City | € 25M |
| 17/07/2013 | Óscar Ustari | Goalkeeper | Boca Juniors | Almeria | Free |
| 15/07/2013 | Markus Steinhöfer | Midfielder | Basel | Betis | Free |
| 14/07/2013 | Thiago Alcántara | Midfielder | Barcelona | Bayern Munich | € 25M |
| 14/07/2013 | Valerón | Midfielder | Deportivo La Coruña | Las Palmas | Free |
| 12/07/2013 | Asier Illarramendi | Midfielder | Real Sociedad | Real Madrid | € 30M |
| 12/07/2013 | Suso | Midfielder | Liverpool | Almeria | Loan |
| 12/07/2013 | Oriol Romeu | Midfielder | Chelsea | Valencia | Loan |
| 11/07/2013 | Rafinha | Midfielder | Barcelona | Celta | Loan |
| 11/07/2013 | Haris Seferovic | Forward | Fiorentina | Real Sociedad | € 3M |
| 11/07/2013 | Callejón | Forward | Real Madrid | Napoli | € 9.5M |
| 11/07/2013 | Rodri | Forward | Barcelona B | Almeria | Loan |
| 11/07/2013 | Sergio Escudero | Defender | Schalke | Getafe | € 500K |
| 11/07/2013 | Martín Demichelis | Defender | Malaga | Atlético Madrid | Free |
| 11/07/2013 | Roque Santa Cruz | Forward | Manchester City | Malaga | Free |
| 10/07/2013 | Gerard Deulofeu | Forward | Barcelona | Everton | Loan |
| 09/07/2013 | N. Castillo | Forward | Leon | Rayo Vallecano | |
| 09/07/2013 | C. Bacca | Forward | Sevilla | Club Brugge | € 7M |
| 09/07/2013 | Giovani dos Santos | Forward | Mallorca | Villarreal | € 6M |
| 09/07/2013 | Joel Goalkeeper | Goalkeeper | Atlético Madrid | Everton | € 4M |
| 08/07/2013 | David Villa | Forward | Barcelona | Atlético Madrid | € 5M |
| 08/07/2013 | Éric Abidal | Defender | Barcelona | Monaco | Free |
| 06/07/2013 | Bojan Krkic | Forward | Barcelona | Ajax | Loan |
| 06/07/2013 | Fernando Tissone | Midfielder | Mallorca | Malaga | Free |
| 06/07/2013 | Jérémy Toulalan | Midfielder | Malaga | Monaco | € 5M |
| 06/07/2013 | Manu Del Moral | Forward | Sevilla | Elche | Loan |
| 06/07/2013 | Miroslav Stevanović | Midfielder | Sevilla | Elche | Loan |
| 05/07/2013 | Florian Lejeune | Defender | Villarreal | Brest | Loan |
| 05/07/2013 | Guillermo Sara | Goalkeeper | Atl. Rafaela | Betis | € 700K |
| 05/07/2013 | Tomás Pina | Midfielder | Mallorca | Villarreal | € 5M |
| 05/07/2013 | Pedro Ríos | Forward | Levante | Villarreal | N/A |
| 05/07/2013 | Diego Mariño | Goalkeeper | Villarreal | Valldolid | N/A |
| 05/07/2013 | Gai Assulin | Midfielder | Racing Santander | Granada | N/A |
| 05/07/2013 | Oriol Riera | Forward | Alcorcon | Osasuna | € 700K |
| 05/07/2013 | José Ángel | Defender | Roma | Real Sociedad | Loan |
| 04/07/2013 | Bojan Jokic | Defender | Chievo | Villarreal | Free |
| 04/07/2013 | Bobley Anderson Allègne | Midfielder | Wydad Casablanca | Malaga | € 1M |
| 03/07/2013 | Kike Sola | Forward | Osasuna | Athletic | N/A |
| 03/07/2013 | Alejandro Domínguez | Forward | Rayo Vallecano | Olympiakos | Free |
| 02/07/2013 | Muniesa | Defender | Barcelona | Stoke City | Free |
| 02/07/2013 | Pozuelo | Midfielder | Betis | Swansea City | Free |
| 01/07/2013 | Andreas Ivanschitz | Midfielder | Mainz | Levante | Free |
| 01/07/2013 | Andrés Palop | Goalkeeper | Sevilla | Bayer Leverkusen | Free |
| 01/07/2013 | Joan Oriol | Defender | Villarreal | Osasuna | Free |
| 01/07/2013 | Vadim Demidov | Defender | Celta | Eintracht Frankfurt | End of Loan |
| 01/07/2013 | Ezequiel | Midfielder | SC Freiburg | Betis | End of Loan |
| 01/07/2013 | Ibrahim Afellay | Midfielder | Schalke | Barcelona | End of Loan |
| 01/07/2013 | Anthony Annan | Midfielder | Osasuna | Schalke | End of Loan |
| 01/07/2013 | Sergio Escudero | Defender | Getafe | Schalke | End of Loan |
| 01/07/2013 | Etxeita | Defender | Elche | Athletic Bilbao | N/A |
| 01/07/2013 | Javi Fuego | Midfielder | Rayo Vallecano | Valencia | Free |
| 01/07/2013 | Gustavo Munúa | Goalkeeper | Levante | Fiorentina | Free |
| 01/07/2013 | Fernando Llorente | Forward | Athletic Bilbao | Juventus | Free |
| 29/06/2013 | Jonathan De Guzmán | Midfielder | Villarreal | Swansea City | Loan |
| 28/06/2013 | Balenziaga | Defender | Valladolid | Athletic Bilbao | Free |
| 28/06/2013 | Emir Spahic | Defender | Sevilla | Bayer Leverkusen | € 400K |
| 28/06/2013 | Vitolo | Forward | Las Palmas | Sevilla | Free |
| 28/06/2013 | Marko Marin | Midfielder | Chelsea | Sevilla | Loan |
| 28/06/2013 | Jordi Amat | Defender | Espanyol | Swansea City | € 2.9M |
| 27/06/2013 | G. García | Defender | Valladolid | Caldas | Loan |
| 27/06/2013 | Charles | Forward | Almeria | Celta | € 1M |
| 27/06/2013 | Isco | Midfielder | Malaga | Real Madrid | € 30M |
| 27/06/2013 | Raúl Baena | Midfielder | Espanyol | Rayo Vallecano | Free |
| 26/06/2013 | Zakarya Bergdich | Defender | RC Lens | Valladolid | Free |
| 26/06/2013 | Beñat | Midfielder | Betis | Athletic Bilbao | € 8M |
| 24/06/2013 | Joan Verdú | Midfielder | Espanyol | Betis | Free |
| 23/06/2013 | Iago Aspas | Forward | Celta | Liverpool | € 8.2M |
| 23/06/2013 | Luis Alberto | Forward | Sevilla | Liverpool | € 8M |
| 23/06/2013 | Jairo | Forward | Racing Santander | Sevilla | € 2.5M |
| 21/06/2013 | Javi Jiménez | Goalkeeper | Murcia | Levante | N/A |
| 20/06/2013 | Andreu Fontàs | Defender | Barcelona | Celta | € 1M |
| 20/06/2013 | Luna | Defender | Sevilla | Aston Villa | € 2M |
| 20/06/2013 | Piti | Forward | Rayo Vallecano | Granada | Free |
| 19/06/2013 | Jordan Lotiès | Defender | Nancy | Osasuna | Free |
| 19/06/2013 | Fuentes | Defender | Cordoba | Espanyol | N/A |
| 19/06/2013 | Abraham | Midfielder | Alcorcon | Espanyol | N/A |
| 18/06/2013 | Issam El Adoua | Defender | Vitoria Guimaraes | Levante | Free |
| 13/06/2013 | Joaquín | Midfielder | Malaga | Fiorentina | € 2M |
| 12/06/2013 | Manuel Iturra | Midfielder | Malaga | Granada | Free |
| 11/06/2013 | Jesús Navas | Midfielder | Sevilla | Manchester City | € 20M |
| 05/06/2013 | Adrian | Goalkeeper | Betis | West Ham | Free |
| 05/06/2013 | Tino Costa | Midfielder | Valencia | Spartak Moscow | € 6.5M |
| 03/06/2013 | Neymar | Forward | Santos | Barcelona | € 57M |
| 03/06/2013 | Daniel Carvajal | Defender | Bayer Leverkusen | Real Madrid | € 6.5M |
| 01/06/2013 | Sueliton | Defender | Rayo Vallecano | Criciuma | Free |
| 31/05/2013 | Radamel Falcao | Forward | Atlético Madrid | Monaco | € 60M |
| 28/05/2013 | Ricardo Carvalho | Defender | Real Madrid | Monaco | Free |
| 23/05/2013 | Cristian Zapata | Defender | Villarreal | AC Milan | € 6M |
| 22/05/2013 | Amorebieta | Defender | Athletic Bilbao | Fulham | Free |
